Kisuke Urahara

Kisuke Urahara is a supporting protagonist in the anime/manga series Bleach. He is the former captain of the 12th Division, as well as the founder and 1st President of the Shinigami Research and Development Institute. Kisuke was originally a Soul Reapers captain, but ended up being exiled from the Soul Society after some of his inventions didn't go over too well with the other Soul Reapers. ... Kisuke actually recreates the gigai that he was expelled for creating and gives it to Rukia Kuchiki.

Hand-to-Hand combat, or Hakuda, and Speed Techniques, more specifically Shunpo,.
 * 1) Swordsmanship, to the point where Ulquiorra Cifer, the fourth Espada, would rather not fight Urahara based on this alone,